LA-ICP-MS analyses of rutile inclusions in detrital corundum: application of the Zr-in-rutile thermometer
Tamás Mikes, Klaus
Simon, Hilmar von Eynatten (GZG, Universität Göttingen)
István Oláh
(ELTE Budapest, Dept. of Petrology/Geochemistry)
Talk by Tamás Mikes in MN 16, on Tuesday, 23rd January 2007, 16:15h
Quantification of element concentrations in mineral or melt inclusions from
LA-ICP-MS analyses normally requires independent determination of an inner standard
element in that inclusion by a different technique (typically electron microprobe).
Yet in sedimentary provenance studies it is an elaborate task to prepare the
necessary amount of grains for such surficial analyses.
We selected the case of the Miocene clastics of the Pannonian Basin, and used
LA-ICP-MS to examine the trace element budget in individual, detrital corundum
crystals and their rutile inclusions, taking the advantage that both minerals
have a very simple main element matrix.
In the talk, a novel use of near-stoichiometric mineral compositions for the
LA-ICP-MS inner standardization procedure will be evaluated through the mineral
chemical data. We will examine if the in-situ, single-grain Zr-in-rutile thermometer
is applicable on this rare type of inclusions, and how the obtained data compare
with independent results from the electron microprobe.